SYNTHESIS AND CHARACTERIZATION OF THE CHARGE TRANSFER COMPLEXES POLYVINYL CARBAZOLE WITH TRINITROFLUORENONE
DOI:
https://doi.org/10.4314/jfas.v12i1.23Keywords:
Electroluminescent; PVK; Charge transfer complex; Electron donor-acceptor.Abstract
Carbazole based polymers are materials of considerable scientific and industrial interest due to their attractive features, such as hole-transporting, high charge-carrier mobility, and electroluminescent properties.
Poly (N-vinyl carbazole) (PVK) is easily synthesized, soluble in common organic solvents, poly (N-vinyl carbazole)/2,4,7-trinitro-9-fluorenone (PVK/TNF) charge transfer complex is one of the best-known organic photos conducting materials for application in electrophotography. In the present research, a spectrophotometric method applied for the study of (colored charge transfer complexes) CTC of PVK with TNF reveals the formation of 1:1 (A:D) complex, the formation of CTC with PVK and TNF from the conductivity of the CT Complex. The concentration of the donor is affected when it reacts with the acceptor and that when we increase the concentration of the donor.
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Spectroscopy 2006, 65(5):1148-1153, doi: 10.1016/j.saa.2005.12.037
[3] Pandeeswaran, M., El‐Mossalamy, E. H., & Elango, K. P. Spectroscopic studies on the
dynamics of charge‐transfer interaction of pantoprazole drug with DDQ and Iodine.
International Journal of Chemical Kinetics.,2009, 41(12), 787-799.
[4] Mulliken R.S, J. Am, Chem. Soc., 1950, 72 (1), 600-608.
[5] Mulliken R.S, Pearson WB. Molecular Complexes, Wiley Publishers., 1969.
[6] Foster R, Charge Transfer Complexes, Academic Press.,1969.
[7] Reffas H, Benabdallah T, Al-Taiar A H, Hadj Youcef M. Physics and Chemistry of
Liquids., 2007, 45(6),641-648, doi: 10.1080/00319100601137221
[8] Eychmüller, A., & Rogach, A. L. Chemistry and photophysics of thiol-stabilized
II-VI semiconductor nanocrystals. Pure and Applied Chemistry, 2000, 72(1-2),179-188.
[9] Brédas, J. L., Calbert, J. P., da Silva Filho, D. A., & Cornil, J. Organic semiconductors: A
theoretical characterization of the basic parameters governing charge transport.
Proceedings of the National Academy of Sciences, 2002, 99(9),5804-5809.
[10] Lee, C. S. Application of charge transfer complexes in organic optoelectronic devices.
In Solid-State and Organic Lighting (pp. DTu4C-2). Optical Society of America, 2014.
[11] Florian W, The Journal of Physical Chemistry Letters, 2010,1(20), 2999-3003.
[12] Carsten D, Strobel T, Vladimir D. Advanced materials, 2010, 22(37),4097- 4111.
[13] Nagai A, Chemical Communications, 2015, 51 (59), 1868-11871.
[14] M. Al-Enizzi, S. N. Theia'a, and S. Thabit, Al-Ghabsha. Jordan Journal of Chemistry,
2012,7(1),87-102.
[15] Dillon, R. Spectroscopy of Photovoltaic Materials: Charge-Transfer Complexes and
Titanium Dioxide, Doctoral dissertation, UC Riverside,2013.
[16] Nanova, D., Beck, S., Fuchs, A., Glaser, T., Lennartz, C., Kowalsky, W., Kroeger, M.
Charge transfer in thin films of donor–acceptor complexes studied by infrared
spectroscopy. Organic electronics, 2012, 13(7),1237-1244.
[17] Arslan, M., & Masnovi, J. Charge transfer complex formation between p-chloranil and
1, n-di (9-anthryl) alkanes. Spectrochimica Acta Part A: Molecular and Biomolecular
Spectroscopy, 2006,64(3),711-716.
[18] Arslan, M., Atak, F. B., & Yakuphanoglu, F. Synthesis and refractive index dispersion
properties of the N, N′, N ″-trinaphthylmethyl melamine-DDQ complex thin film.
Optical Materials, 2007, 29(5),516-520.
[19] Meerholz, K., Volodin, B. L., Kippelen, B., & Peyghambarian, N. A photorefractive
polymer with high optical gain and diffraction efficiency near 100%. Nature, 1994,
371(6497), 497.
[20] Ionita, I., Albu, A. M., & Radulescu, C. Synthesis and Characterization of New
Carbazole Derivative for Photorefractive Materials. Rev. Chim, 2013,64, 612-619.
[21] Liu, Y., Nishiura, M., Wang, Y., & Hou, Z. π-Conjugated aromatic enynes as a
single-emitting component for white electroluminescence. Journal of the American
Chemical Society, 2006,128(17), 5592-5593.
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[23] Wang Y. Photoconductivity of fullerene-doped polymers. Nature, 1992, 356(6370), 585.
[24] B. Serge. Macromolecular Theory and Simulations, 2011,20(1),13-18.
[25] Yang Y, Li G. Springer-Verlag Berlin AN, 2016.
[26] Ribierre, J. C., Aoyama, T., Muto, T., Imase, Y., & Wada, T. Charge transport properties
In liquid carbazole. Organic Electronics, 2008, 9(3),396-400.
[27] Basavaraja C, Thinh PX, Huh DS. Macromolecular Research, 2013, 21574-581.
[28] S. Liu, J. Shi, EricW. Forsythe, S. M. Blomquist, D. Chiu, Polymer Synthetic Metals,
2009,159 ,1438-1442.
[29] Grigoras, A. G., & Barboiu, V. Influence of acceptor functionality on charge transfer
interactions in mixtures of poly (9-vinylcarbazole) with nitroaromatic compounds.
Central European Journal of Chemistry, 2012,10(2), 313-319.
[30] Bakulin AA, Elizarov SG, Khodarev AN, Martyanov DS, Golovnin IV, Paraschuk DY,
Triebel MM, Tolstov IV, Frankevich E L, Arnautov SA, Nechvolodova E M. Synth.
Met, 2004,147, 221.
[31] Im, C., Lupton, J. M., Schouwink, P., Heun, S., Becker, H., & Bässler, H. Fluorescence
dynamics of phenyl-substituted polyphenylenevinylene- trinitrofluorenone blend
systems. The Journal of chemical physics, 2002, 117(3), 1395-1402.
[32] Mulliken RS, J. Am. Chem. Soc, 1952,74,811.
[33] Mulliken RS, J. Phys. Chem, 1952, 56, 801.
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Published
2019-12-24
How to Cite
MAGHCHICHE, A.; SAKKI, B.; NASRI, R.; BOURAS, O.; HAOUAM, A. SYNTHESIS AND CHARACTERIZATION OF THE CHARGE TRANSFER COMPLEXES POLYVINYL CARBAZOLE WITH TRINITROFLUORENONE. Journal of Fundamental and Applied Sciences, [S. l.], v. 12, n. 1, p. 389–398, 2019. DOI: 10.4314/jfas.v12i1.23. Disponível em: https://www.jfas.info/index.php/JFAS/article/view/344. Acesso em: 10 dec. 2024.
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